Skip to main content
Workforce LibreTexts

5.4: Materials Used in Soldering and Brazing

  • Page ID
    41462
  • \( \newcommand{\vecs}[1]{\overset { \scriptstyle \rightharpoonup} {\mathbf{#1}} } \)

    \( \newcommand{\vecd}[1]{\overset{-\!-\!\rightharpoonup}{\vphantom{a}\smash {#1}}} \)

    \( \newcommand{\dsum}{\displaystyle\sum\limits} \)

    \( \newcommand{\dint}{\displaystyle\int\limits} \)

    \( \newcommand{\dlim}{\displaystyle\lim\limits} \)

    \( \newcommand{\id}{\mathrm{id}}\) \( \newcommand{\Span}{\mathrm{span}}\)

    ( \newcommand{\kernel}{\mathrm{null}\,}\) \( \newcommand{\range}{\mathrm{range}\,}\)

    \( \newcommand{\RealPart}{\mathrm{Re}}\) \( \newcommand{\ImaginaryPart}{\mathrm{Im}}\)

    \( \newcommand{\Argument}{\mathrm{Arg}}\) \( \newcommand{\norm}[1]{\| #1 \|}\)

    \( \newcommand{\inner}[2]{\langle #1, #2 \rangle}\)

    \( \newcommand{\Span}{\mathrm{span}}\)

    \( \newcommand{\id}{\mathrm{id}}\)

    \( \newcommand{\Span}{\mathrm{span}}\)

    \( \newcommand{\kernel}{\mathrm{null}\,}\)

    \( \newcommand{\range}{\mathrm{range}\,}\)

    \( \newcommand{\RealPart}{\mathrm{Re}}\)

    \( \newcommand{\ImaginaryPart}{\mathrm{Im}}\)

    \( \newcommand{\Argument}{\mathrm{Arg}}\)

    \( \newcommand{\norm}[1]{\| #1 \|}\)

    \( \newcommand{\inner}[2]{\langle #1, #2 \rangle}\)

    \( \newcommand{\Span}{\mathrm{span}}\) \( \newcommand{\AA}{\unicode[.8,0]{x212B}}\)

    \( \newcommand{\vectorA}[1]{\vec{#1}}      % arrow\)

    \( \newcommand{\vectorAt}[1]{\vec{\text{#1}}}      % arrow\)

    \( \newcommand{\vectorB}[1]{\overset { \scriptstyle \rightharpoonup} {\mathbf{#1}} } \)

    \( \newcommand{\vectorC}[1]{\textbf{#1}} \)

    \( \newcommand{\vectorD}[1]{\overrightarrow{#1}} \)

    \( \newcommand{\vectorDt}[1]{\overrightarrow{\text{#1}}} \)

    \( \newcommand{\vectE}[1]{\overset{-\!-\!\rightharpoonup}{\vphantom{a}\smash{\mathbf {#1}}}} \)

    \( \newcommand{\vecs}[1]{\overset { \scriptstyle \rightharpoonup} {\mathbf{#1}} } \)

    \( \newcommand{\vecd}[1]{\overset{-\!-\!\rightharpoonup}{\vphantom{a}\smash {#1}}} \)

    \(\newcommand{\avec}{\mathbf a}\) \(\newcommand{\bvec}{\mathbf b}\) \(\newcommand{\cvec}{\mathbf c}\) \(\newcommand{\dvec}{\mathbf d}\) \(\newcommand{\dtil}{\widetilde{\mathbf d}}\) \(\newcommand{\evec}{\mathbf e}\) \(\newcommand{\fvec}{\mathbf f}\) \(\newcommand{\nvec}{\mathbf n}\) \(\newcommand{\pvec}{\mathbf p}\) \(\newcommand{\qvec}{\mathbf q}\) \(\newcommand{\svec}{\mathbf s}\) \(\newcommand{\tvec}{\mathbf t}\) \(\newcommand{\uvec}{\mathbf u}\) \(\newcommand{\vvec}{\mathbf v}\) \(\newcommand{\wvec}{\mathbf w}\) \(\newcommand{\xvec}{\mathbf x}\) \(\newcommand{\yvec}{\mathbf y}\) \(\newcommand{\zvec}{\mathbf z}\) \(\newcommand{\rvec}{\mathbf r}\) \(\newcommand{\mvec}{\mathbf m}\) \(\newcommand{\zerovec}{\mathbf 0}\) \(\newcommand{\onevec}{\mathbf 1}\) \(\newcommand{\real}{\mathbb R}\) \(\newcommand{\twovec}[2]{\left[\begin{array}{r}#1 \\ #2 \end{array}\right]}\) \(\newcommand{\ctwovec}[2]{\left[\begin{array}{c}#1 \\ #2 \end{array}\right]}\) \(\newcommand{\threevec}[3]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \end{array}\right]}\) \(\newcommand{\cthreevec}[3]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \end{array}\right]}\) \(\newcommand{\fourvec}[4]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \\ #4 \end{array}\right]}\) \(\newcommand{\cfourvec}[4]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \\ #4 \end{array}\right]}\) \(\newcommand{\fivevec}[5]{\left[\begin{array}{r}#1 \\ #2 \\ #3 \\ #4 \\ #5 \\ \end{array}\right]}\) \(\newcommand{\cfivevec}[5]{\left[\begin{array}{c}#1 \\ #2 \\ #3 \\ #4 \\ #5 \\ \end{array}\right]}\) \(\newcommand{\mattwo}[4]{\left[\begin{array}{rr}#1 \amp #2 \\ #3 \amp #4 \\ \end{array}\right]}\) \(\newcommand{\laspan}[1]{\text{Span}\{#1\}}\) \(\newcommand{\bcal}{\cal B}\) \(\newcommand{\ccal}{\cal C}\) \(\newcommand{\scal}{\cal S}\) \(\newcommand{\wcal}{\cal W}\) \(\newcommand{\ecal}{\cal E}\) \(\newcommand{\coords}[2]{\left\{#1\right\}_{#2}}\) \(\newcommand{\gray}[1]{\color{gray}{#1}}\) \(\newcommand{\lgray}[1]{\color{lightgray}{#1}}\) \(\newcommand{\rank}{\operatorname{rank}}\) \(\newcommand{\row}{\text{Row}}\) \(\newcommand{\col}{\text{Col}}\) \(\renewcommand{\row}{\text{Row}}\) \(\newcommand{\nul}{\text{Nul}}\) \(\newcommand{\var}{\text{Var}}\) \(\newcommand{\corr}{\text{corr}}\) \(\newcommand{\len}[1]{\left|#1\right|}\) \(\newcommand{\bbar}{\overline{\bvec}}\) \(\newcommand{\bhat}{\widehat{\bvec}}\) \(\newcommand{\bperp}{\bvec^\perp}\) \(\newcommand{\xhat}{\widehat{\xvec}}\) \(\newcommand{\vhat}{\widehat{\vvec}}\) \(\newcommand{\uhat}{\widehat{\uvec}}\) \(\newcommand{\what}{\widehat{\wvec}}\) \(\newcommand{\Sighat}{\widehat{\Sigma}}\) \(\newcommand{\lt}{<}\) \(\newcommand{\gt}{>}\) \(\newcommand{\amp}{&}\) \(\definecolor{fillinmathshade}{gray}{0.9}\)

    Materials Used in Soldering and Brazing in HVAC

         The materials used in soldering and brazing play a critical role in ensuring strong, leak-free, and durable joints in HVAC systems. Choosing the right metals and alloys, fluxes, and filler materials is essential for optimal performance. Below is a detailed breakdown of each category.


     

    Metals and Alloys Used in Soldering and Brazing

         HVAC systems use a variety of metals and alloys, depending on the application. Some metals are better suited for electrical connections, while others are used for high-pressure refrigerant lines or gas piping.

     

    Common Metals Used in HVAC Soldering and Brazing

    Metal Properties Common HVAC Applications
    Copper Excellent thermal & electrical conductivity, corrosion-resistant Refrigerant lines, water pipes, and electrical connections
    Aluminum Lightweight, strong, and corrosion-resistant Some refrigerant lines and heat exchangers
    Silver High strength, excellent conductivity, and corrosion resistance High-performance HVAC joints, electrical components
    Nickel High resistance to oxidation and corrosion Specialty HVAC systems, high-temperature applications

     

    Common Alloys Used in HVAC Soldering and Brazing

    Alloy Composition Properties Common HVAC Applications
    Brass Copper + Zinc Strong, corrosion-resistant Used for fittings, valves, and connections
    Bronze Copper + Tin Durable, resistant to corrosion Used in some pipe joints and HVAC components
    Phosphor Bronze Copper + Tin + Phosphorus Excellent fatigue resistance Used in brazing joints for refrigerant lines
    Silicon Bronze Copper + Silicon High strength, good corrosion resistance Used for brazing HVAC piping

     

    Note: Copper is the most commonly used base metal in HVAC applications due to its high conductivity, resistance to corrosion, and ease of joining using soldering and brazing techniques.

     


     

    Fluxes Used in Soldering and Brazing

    Flux is a chemical compound applied to metal surfaces before soldering or brazing. It serves three primary functions:

    1. Cleans the metal surface by removing oxides and contaminants.
    2. Prevents oxidation during heating, which can weaken joints.
    3. Promotes adhesion by helping the filler material flow evenly.

     

    Types of Flux Used in HVAC

    Type of Flux Composition Characteristics Common Uses
    Rosin Flux Natural resin (from pine trees) Mild, leaves residue, non-corrosive Used in electrical soldering
    Acid Flux (Hydrochloric Acid-Based) Acid-based chemical Aggressive, strong cleaning action, can corrode over time Used for plumbing and HVAC pipe soldering (copper)
    Water-Soluble Flux Organic acid + activators Easier to clean, moderate strength Used in HVAC pipe brazing and soldering
    Boric Acid Flux Borax-based High-temperature resistance, protects against oxidation Used in brazing steel and high-strength alloys
    Fluoride-Based Flux Fluoride + active compounds Withstands extreme heat, prevents oxidation at high temperatures Used in aluminum and silver brazing

     

    Choosing the Right Flux for HVAC Applications

    • For copper pipe soldering: Acid-based or water-soluble fluxes are preferred.
    • For brazing aluminum: Fluoride-based flux is required due to aluminum’s oxidation properties.
    • For high-strength joints: Boric acid flux is ideal for extreme temperature applications.

     

    Important Safety Note: Acid flux can cause corrosion over time if not properly cleaned after soldering. Always wipe excess flux off with a damp cloth or a neutralizing agent.

     


     

    Filler Materials Used in Soldering and Brazing

         The filler material is the metal alloy that melts during soldering or brazing to form the bond between metal parts. Different filler materials are selected based on their melting point, strength, and compatibility with base metals.

     

    Soldering Filler Materials (Low-Temperature, Below 450°C / 842°F)

    Solder Type Composition Characteristics Common HVAC Applications
    Lead-Based Solder 60% Tin + 40% Lead Lower melting point, smooth flow Used in legacy HVAC systems (now phased out due to health concerns)
    Lead-Free Solder Tin + Silver or Tin + Copper Higher melting point, environmentally friendly Used in modern HVAC electrical connections
    Tin-Silver Solder 96% Tin + 4% Silver Stronger bond, corrosion-resistant Used for electrical soldering in HVAC control systems
    Tin-Copper Solder 97% Tin + 3% Copper Good alternative to lead-based solder Used for non-refrigerant HVAC applications

     

    Note: The use of lead-based solder has been largely discontinued due to its toxicity. Lead-free alternatives are now the standard.

     

    Brazing Filler Materials (High-Temperature, Above 450°C / 842°F)

    Brazing Rod Type Composition Characteristics Common HVAC Applications
    Silicon Bronze Rods Copper + Silicon High strength, corrosion resistance Used for brazing copper HVAC pipes
    Silver Brazing Rods 15% or 45% Silver + Copper + Zinc Lower melting point, strong joints Used for refrigerant line brazing
    Aluminum Brazing Rods Aluminum + Zinc + Magnesium High corrosion resistance, works on aluminum Used in aluminum evaporator coils
    Nickel-Silver Rods Nickel + Silver Heat-resistant, strong bond Used for brazing stainless steel in high-temperature HVAC systems
    Phosphorus-Copper Brazing Rods Copper + Phosphorus Self-fluxing on copper, easy to use Commonly used for copper-to-copper HVAC joints

     

    Choosing the Right Filler Material

    • For refrigerant lines: 15% or 45% silver brazing rods provide a strong, leak-proof joint.
    • For copper-to-copper joints: Phosphorus-copper rods are ideal since they do not require additional flux.
    • For aluminum components: Aluminum brazing rods must be used, along with a fluoride-based flux.
    • For high-temperature applications: Nickel-silver brazing rods offer heat resistance and durability.

     

    Important Tip: The melting point of the filler material must always be lower than the base metal to avoid damaging the pipe or component being joined.

     

    Summary

         Understanding the right materials for soldering and brazing is essential for any HVAC technician. Copper, aluminum, and brass are the most common metals used, while silver, tin, and phosphorus-based alloys serve as strong filler materials. Flux selection ensures clean joints and prevents oxidation, while proper filler choice ensures durability and system efficiency. By using the correct combination of these materials, HVAC technicians can create strong, leak-free connections that withstand extreme temperatures and pressures, ensuring the longevity of heating and cooling systems.


    This page titled 5.4: Materials Used in Soldering and Brazing is shared under a CC BY-NC 4.0 license and was authored, remixed, and/or curated by Richard Valenzuela.